A versatile synthesis of 1,6 - d-oligomannosides featuring the 1,4-disubstituted triazole ring as interglycosidic tether is presented via iterative copper(I)-catalyzed azide-alkyne cycloaddition. Free hydroxy hexamannoside and decamannoside featuring a capping 6-deoxymannose fragment have been prepared and characterized.
Studies toward the synthesis of inhibitors of mycobacterium tuberculosis cell-wall biosynthesis: The assembly of triazole-linked 1,6-a-D-oligomannosides via click CuAAC
CHAMBERY, Angela;
2009
Abstract
A versatile synthesis of 1,6 - d-oligomannosides featuring the 1,4-disubstituted triazole ring as interglycosidic tether is presented via iterative copper(I)-catalyzed azide-alkyne cycloaddition. Free hydroxy hexamannoside and decamannoside featuring a capping 6-deoxymannose fragment have been prepared and characterized.File in questo prodotto:
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