Both anomers of methyl 3-acetamido-3, 6-dideoxy-L-galactopyranoside and of methyl 3-acetamido-3, 6-dideoxy-L-gulopyranoside have been prepared by conversion of easily accessible derivatives of methyl 6-deoxy-(α and β)-L-galactopyranosides into 3-uloses and reduction of the corresponding 0-methyloximes. The 1H and 13C NMR data of the four 3-acetamido methyl glycosides have been given. © 1995, Taylor & Francis Group, LLC. All rights reserved.
SYNTHESIS OF METHYL 3-ACETAMIDO-3,6-DIDEOXY-L-GALACTOPYRANOSIDES AND OF METHYL 3-ACETAMIDO-3,6-DIDEOXY-L-GULOPYRANOSIDES BY REDUCTION OF 3-ULOSE O-METHYLOXIMES
MONACO, Pietro
1995
Abstract
Both anomers of methyl 3-acetamido-3, 6-dideoxy-L-galactopyranoside and of methyl 3-acetamido-3, 6-dideoxy-L-gulopyranoside have been prepared by conversion of easily accessible derivatives of methyl 6-deoxy-(α and β)-L-galactopyranosides into 3-uloses and reduction of the corresponding 0-methyloximes. The 1H and 13C NMR data of the four 3-acetamido methyl glycosides have been given. © 1995, Taylor & Francis Group, LLC. All rights reserved.File in questo prodotto:
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