The fate of fixed carbon during the fluidized-bed combustion of a coal and two waste-derived fuels

The fate of fixed carbon during fluidized-bed combustion of a bituminous coal and two alternative fuels. a refuse-derived fuel (RDF) and a tyre-derived fuel (TDF), was investigated. A simple model was developed based on the assumption that fixed carbon present in the bed could be lumped into a coarse particles phase and a fine carbon phase. The model is based on a network of paths representing the generation of coarse and fine char particles from the parent fuel by primary fragmentation, the fine particle production by comminution of coarse char, the combustion of the coarse and of the fine char particles, as well as the elutriation of fines. Results of computations of carbon conversion were in good agreement with those measured in batchwise experiments with each of the three fuels. Conversion of the coal takes place mainly via fuel devolatilization to coarse char which further reacts to gaseous products. Conversion of TDF occurs via the generation, upon devolatilization, of amultitude of fines which eventually undergo combustion and elutriation. The phenomenology associated with RDF fluidized-bed combustion is intermediate between those of coal and TDF. The resulting framework for the evaluation of fixed carbon balance helps in identifying key factors in the conversion of such widely different fuels. © 1996 Combustion Institute.