A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the "random first-order" scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.
Inverse freezing in mean-field models of fragile glasses
SELLITTO, Mauro
2006
Abstract
A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the "random first-order" scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.File in questo prodotto:
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