A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the "random first-order" scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.

Inverse freezing in mean-field models of fragile glasses

SELLITTO, Mauro
2006

Abstract

A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the "random first-order" scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11591/189251
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