On 17 January 2002, the city of Goma was partly destroyed by two of the several lava flows erupted from a roughly N-S oriented fracture system opened along the southern flank of Mount Nyiragongo (Democratic Republic of Congo), in the western branch of the East African rift system. A humanitarian and scientific response was promptly organized by international, governmental, and nongovernmental agencies coordinated by the United Nations and the European Union. Among the different scientific projects undertaken to study the mechanisms triggering this and possible future eruptions, we focused on the isotopic (He, C, and Ar) analysis of the magmatic-hydrothermal and cold gas discharges related to the Nyiragongo volcanic system, the Kivu and Virunga region. The studied area includes the Nyiragongo volcano, its surroundings, and peripheral areas inside and outside the rift. They have been subdivided into seven regions characterized by distinct He/He (expressed as R/Rair) ratios and/or δ13 C-CO2 values. The Nyiragongo summit crater fumaroles, whose R/Rair and δ13 C-CO2 values are up to 8.73 and from -3.5% to -4.0% VPDB, respectively, show a clear mantle, mid-ocean ridge basalt (MORB)-like contribution. Similar mantle-like He isotopic values (6.5-8.3 R/Rair) are also found in CO2-rich gas emanations (mazukus) along the northern shoreline of Lake Kivu main basin, whereas the 13δC- CO2 values range from -5.3% to -6.8% VPDB. The mantle influence progressively decreases in (1) dissolved gases of Lake Kivu (2.6-5.5 R/R air) and (2) the distal gas discharges within and outside the two sides of the rift (from 0.1 to 1.7 R/Rair). Similarly, δ13 C-CO2 ratios of the peripheral gas emissions are lighter (from -5.9% to - 11.6% VPDB) than those of the crater fumaroles. Therefore, the spatial distribution of He and C signatures in the Lake Kivu region is mainly produced by mixing of mantle-related (e.g., Nyiragongo crater fumaroles and/or mazukus gases) and crustal-related (e.g., gas discharges in the Archean craton) fluids. The CO2/He ratio (up to 10×10) is 1 order of magnitude higher than those found in MORB, and it is due to the increasing solubility of CO2 in the foiditic magma feeding the Nyiragongo volcano. However, the exceptionally high 40Ar */He ratio (up to 8.7) of the Nyiragongo crater fumaroles may be related to the difference between He and Ar solubility in the magmatic source. The results of the present investigation suggest that in this area the uprising of mantle-originated f luids seems strongly controlled by regional tectonics in relation to the geodynamic assessment of the rift. These fluids are mainly localized in a relatively small zone between Lake Kivu and Nyiragongo volcano, with important implications in terms of volcanic activity. Copyright 2010 by the American Geophysical Union.

Gas isotopic signatures (He, C, and Ar) in the Lake Kivu region (western branch of the East African rift system): Geodynamic and volcanological implications

TEDESCO, Dario;
2010

Abstract

On 17 January 2002, the city of Goma was partly destroyed by two of the several lava flows erupted from a roughly N-S oriented fracture system opened along the southern flank of Mount Nyiragongo (Democratic Republic of Congo), in the western branch of the East African rift system. A humanitarian and scientific response was promptly organized by international, governmental, and nongovernmental agencies coordinated by the United Nations and the European Union. Among the different scientific projects undertaken to study the mechanisms triggering this and possible future eruptions, we focused on the isotopic (He, C, and Ar) analysis of the magmatic-hydrothermal and cold gas discharges related to the Nyiragongo volcanic system, the Kivu and Virunga region. The studied area includes the Nyiragongo volcano, its surroundings, and peripheral areas inside and outside the rift. They have been subdivided into seven regions characterized by distinct He/He (expressed as R/Rair) ratios and/or δ13 C-CO2 values. The Nyiragongo summit crater fumaroles, whose R/Rair and δ13 C-CO2 values are up to 8.73 and from -3.5% to -4.0% VPDB, respectively, show a clear mantle, mid-ocean ridge basalt (MORB)-like contribution. Similar mantle-like He isotopic values (6.5-8.3 R/Rair) are also found in CO2-rich gas emanations (mazukus) along the northern shoreline of Lake Kivu main basin, whereas the 13δC- CO2 values range from -5.3% to -6.8% VPDB. The mantle influence progressively decreases in (1) dissolved gases of Lake Kivu (2.6-5.5 R/R air) and (2) the distal gas discharges within and outside the two sides of the rift (from 0.1 to 1.7 R/Rair). Similarly, δ13 C-CO2 ratios of the peripheral gas emissions are lighter (from -5.9% to - 11.6% VPDB) than those of the crater fumaroles. Therefore, the spatial distribution of He and C signatures in the Lake Kivu region is mainly produced by mixing of mantle-related (e.g., Nyiragongo crater fumaroles and/or mazukus gases) and crustal-related (e.g., gas discharges in the Archean craton) fluids. The CO2/He ratio (up to 10×10) is 1 order of magnitude higher than those found in MORB, and it is due to the increasing solubility of CO2 in the foiditic magma feeding the Nyiragongo volcano. However, the exceptionally high 40Ar */He ratio (up to 8.7) of the Nyiragongo crater fumaroles may be related to the difference between He and Ar solubility in the magmatic source. The results of the present investigation suggest that in this area the uprising of mantle-originated f luids seems strongly controlled by regional tectonics in relation to the geodynamic assessment of the rift. These fluids are mainly localized in a relatively small zone between Lake Kivu and Nyiragongo volcano, with important implications in terms of volcanic activity. Copyright 2010 by the American Geophysical Union.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11591/187552
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