Copper(I) iodide catalyzed cycloadditions of various combinations of structurally diverse organic azides and terminal alkynes were carried out in a commercially available, polyoxygenated ionic liquid (AMMOENG 100) without addition of free amine. Unlike the previously tested ionic liquids, this solvent led exclusively to the 1,4-disubstituted triazole regioisomer. © Georg Thieme Verlag Stuttgart.
Copper(I)-catalyzed azide-alkyne cycloadditions in ionic liquids under amine-free conditions
CHAMBERY, Angela;
2010
Abstract
Copper(I) iodide catalyzed cycloadditions of various combinations of structurally diverse organic azides and terminal alkynes were carried out in a commercially available, polyoxygenated ionic liquid (AMMOENG 100) without addition of free amine. Unlike the previously tested ionic liquids, this solvent led exclusively to the 1,4-disubstituted triazole regioisomer. © Georg Thieme Verlag Stuttgart.File in questo prodotto:
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